ALTERNATING CURRENT ELECTROLYSIS.

Studies on Alternating Current Electrolysis IV. Mathematical Treatment of Reversible Electron Transfer with Alternating Voltage Control and Distorted Current

A mathemat ica l t r ea tmen t is developed which yields equations re la t ing fa rada ic current , voltage, and t ime when an a l te rna t ing vol tage is appl ied to an e lect rolyt ic cell composed of a p lane and aux i l i a ry electrodes immersed in a solut ion containing in i t ia l ly suppor t ing e lec t ro ly te and only r eve r s ib ly oxidizable or reduc ib le species. Both ox idant ...

Alternating Current Electrolysis of Transition-Metal Carbonyl Complexes: Electrochemically Induced Photochemistry

The complex ligand trans-4-styrylpyridine (trans-SP) is converted into its cis isomer (cis-SP) in the coordinated state upon simple alternating current electrolysis of the rhenium complex Re[(tran~-SP)~(CO)~Cll in acetonitrile/Bu4NC104 in an undivided electrochemical cell. Evidence is presented that this reaction proceeds via an electronically excited state of the complex generated by a cation-...

Alternating Current Electrospraying

Electrospraying has attracted the attention of many researchers, ranging from analytical chemists to physicists, not only because of the rich physics associated with it, but also due to its wide-ranging applicability. Therefore, considerable research has been devoted to exploring this interfacial phenomenon. However, there still are areas of electrospraying that have remained unexplored. Until ...

Alternating Current Theory -

1 November 2001 Alternating Current Theory J R Lucas An alternating waveform is a periodic waveform which alternate between positive and negative values. Unlike direct waveforms, they cannot be characterised by one magnitude as their amplitude is continuously varying from instant to instant. Thus various forms of magnitudes are defined for such waveforms. The advantage of the alternating wavefo...

Flexible Alternating Current Transmission Systems